I got images of the JWST spacecraft (2021-130A) and the Ariane upper stage (2021-130B) last night. They are currently around 2 degrees apart on the sky. JWST is much brighter tonight as the sunshield was being deployed. The magnitude was 14.3 at a range of 687,000 km. From the timings in the NASA blog I think that the sunshield was half out when this image was taken but this implies a magnitude of around 16 or so at L2. Astrometry of the upper stage is valuable since it is not being tracked by radio and I assume it is now passive.