The spacing of the lines is different in the two images and there are several extra weak lines in the one with the close double. There has been a big wavelength shift to the left of about half a field between the two images and we are looking at a different part of the spectrum. (The line on the right in the first spectrum corresponds to the line on the left in the second spectrum. The doubled line is outside the right hand edge of the field in the first spectrum)
See attached
Robin