Very “hand waving” but as I understand it, it is because of the difference in the mechanism. With a core collapse type II supernova the core remains, compressed into a neutron star and the visible spectrum results from the heating of the outer layers of the star, mainly hydrogen, hence the strong Balmer lines. With a type Ia, the white dwarf is completely consumed by the thermonuclear explosion resulting from the increase in pressure just prior to the impending total collapse, converting all the material into heavier elements including silicon, the Si II (and Calcium) lines showing strongly in the visible part of the spectrum.